Polar, Non-Coordinating Ionic Liquids as Solvents for Coordination Polymerization of Olefins
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| Abstract: | Increased polymerization yield is observed in the copolymerization of styrene and CO in ionic liquids (ILs) compared to commonly used molecular solvents using palladium catalysts. Conditions for the copolymerizations were optimized and the effect of changes in the cation and anion of the IL solvent were determined. These results suggest that polar, non-coordinating ILs accelerate olefin polymerization catalyzed by electrophilic, charge-separated catalyst species. |
| Author:
| Kevin H. Shaughnessy, , Marc A. Klingshirn, , Steven J. P'Pool, , John D. Holbrey, and , Robin D. Ro |
| Author Unit:
| Department of Chemistry and the Center for Green Manufacturing, The University of Alabama, Tuscaloos |
| Year: | 2003 |
| Source: | |
| Volume-OnPage: | Chapter 25, pp 300-313 |
| Publication Date:
| August 26, 2003 |
| Keyword: | |
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