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1593
Two new oxamidato-bridged CuII-CuII complexes: Synthesis, structure, spectra, and cyclic voltammetry studies
Two new oxamidato-bridged CuII-CuII complexes: Synthesis, structure, spectra, and cyclic voltammetry studies
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S. Ren, F. H. Li;S. L. Ma
2012
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New oxamido-bridged binuclear CuII-CuII complexes, [Cu(Oxen)Cu(Bipy)2](ClO4)2 (I) and [Cu(Oxen)Cu(4,4′-Bipy)2(H2O)2](ClO4)2 (II) (Oxen is N,N′-bis(2-aminoethyl)oxamide dianion, Bipy = 2,2′-bipyridine, 4,4′-Bipy = 4,4′-bipyridine), have been constructed and structurally characterized by X-ray crystallography. In these two complexes, each Cu2+ ion is located in a slightly distorted square-pyramidal environment. Complex I is extended to two-dimensional by fa...
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