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Excess volumes, mixing viscosities, and excess Gibbs energies of activation of viscous flow of the aqueous binary mixtures of the amides formamide, N-methylformamide, N,N-dimethylformamide, pyrrolidin-2-one, and N-methyl-2-pyrrolidinone were calculated from density and viscosity measurements. The values of these functions point to strong amide?water interactions with formation of a variety of aggregates, the nature of which depends on the extent of substitution of the amides; comparison of the f...
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