|
The photophysical properties of the chromophore-quencher complexes, fac-[(4,4′-R2bpy)ReI(CO)3(LA)]n+ (4,4′-R2bpy = 4,4′-R2-2,2′-bipyridine, R = Me or tBu, and LA = the quinone acceptor ligands, benz[g]- isoquinoline-5,10-dione (BIQD), 2-oxy-1,4-naphthoquinone anion (ONQ-), 1/2 2,6-dihydroxyanthraquinone dianion (AFA2-), or the pyridinium acceptor, 1-methyl-6-oxyquinoline (OQD)) in 1,2-dichloroethane are described. Following ReI &rarr 4,4′-R2bpy metal-to-ligand char...
|